Separating Ethanol
From Water Via Differential Miscibility
The differential miscibility of castor oil in ethanol
and water would be exploited to separate ethanol from water, according to a proposal. Burning the separated ethanol would
produce more energy than would be consumed in the separation process. In contrast, the separation of a small amount of ethanol
(actually an ethanol/water solution poor in ethanol) from water by the conventional process of distillation requires more
energy than can be produced by burning the resulting distillate. As in the process described in the preceding article, "Separating
Ethanol From Water Via Differential Solubility" (LAR-14894), the proposed alcohol/water separation process could be exploited
industrially to produce clean fuel from fermented vegetable matter.
In one version of this process, castor oil would be added
to an ethanol/water solution. The ethanol would mix freely with castor oil, which is insoluble in water. The resulting ethanol/castor-oil
phase, which would contain less than 1 percent water, would collect as the top layer, the bottom layer being the remainder
of the ethanol/water solution somewhat depleted in ethanol. Heating this two-layer mixture to a temperature slightly below
the boiling temperature of ethanol (78.5 °C) would cause the partial pressure of ethanol above the top layer to be much greater
than the partial pressure of either castor oil or water. This vapor-phase ethanol could be condensed in a relatively pure
state.
Although heating an isolated ethanol/water solution like
that in the bottom layer would normally raise the vapor pressure of both ethanol and water above the solution, this would
not be the case in the presence of the top castor-oil/ethanol layer for the following reasons: The amount of water that could
dissolve in the top castor-oil/ethanol layer would increase only slightly upon heating. On the other hand, ethanol could readily
cross the interface between the two layers and enter the top layer. As long as the total mix was kept at a temperature below
the boiling temperature of ethanol (thereby preventing agitation of the layers by boiling), the diffusion of water through
the castor-oil/ethanol phase would be inhibited.
In an alternative version of this concept, the upper
castor-oil/ethanol layer would be skimmed off and heated to obtain the ethanol. Once the ethanol was driven off, the castor
oil could be returned to an ethanol/water solution to dissolve more ethanol to repeat the process. This concept could readily
lend itself to a continuous process. Substances other than castor oil (one of its components perhaps, or another substance)
could be used in this process or to extract other compounds from other mixtures by using this upper-of-two-phases vaporization
technique.
This work was done by Renaldo V. Jenkins of Langley Research Center. No further documentation is available. LAR-14895
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CASTOR OIL SPECIFICATIONS
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Prepared at the 27th JECFA (1983), published
in FNP 28 (1983) and in FNP 52 (1992) Metals and arsenic specifications revised at the 63rd JECFA (2004)
An ADI of 0-0.7 mg/kg bw established at
the 23rd JECFA (1979)
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SYNONYMS |
Ricinus oil; INS No. 1503
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DEFINITION |
The fixed oil obtained from the seed of Ricinus
Communis L. (family Euphorbiaceae) is essentially the triglyceride of ricinoleic
acid.
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C.A.S. number |
8001-79-4
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DESCRIPTION |
Pale yellow or almost colourless, clear, viscous liquid, with a faint, mild odour
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FUNCTIONAL USES |
Carrier solvent, release agent
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CHARACTERISTICS |
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IDENTIFICATION |
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Solubility
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Soluble in 95% ethanol; miscible with absolute ethanol; slightly soluble in light petroleum
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Specific gravity
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0.952 - 0.966 |
Refractive index
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n (20, D): 1.477 - 1.481 |
PURITY |
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Acid value
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Not more than 2 |
Hydroxyl value
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160 - 168 |
Saponification value
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176 - 185 |
Iodine value |
83 - 88 |
Lead |
Not more than 2 mg/kg
Determine using an atomic absorption technique appropriate to the specified
level. The selection of sample size and method of sample preparation may be based on the principles of the method described
in Volume 4, “Instrumental Methods.”
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Date of Peer Review: May 2003
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Ricinus oil |
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CAS # |
8001-79-4
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RTECS # |
FI4100000 |
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UN # |
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EC # |
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TYPES OF HAZARD / EXPOSURE |
ACUTE HAZARDS / SYMPTOMS |
PREVENTION |
FIRST AID / FIRE FIGHTING |
FIRE |
Combustible.
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NO open flames.
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Powder, carbon
dioxide. |
EXPLOSION |
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EXPOSURE |
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Inhalation |
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Skin |
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Eyes |
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Ingestion |
Abdominal pain.
Diarrhoea. Nausea. Vomiting. |
Do not eat, drink,
or smoke during work. |
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SPILLAGE DISPOSAL |
PACKAGING & LABELLING |
Collect leaking
liquid in covered containers. |
EU
Classification UN Classification
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EMERGENCY RESPONSE |
STORAGE |
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IPCS International Programme on Chemical Safety |
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Prepared in the
context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities
© IPCS, CEC 1999
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IMPORTANT DATA |
PHYSICAL STATE; APPEARANCE: VISCOUS COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.
OCCUPATIONAL EXPOSURE LIMITS: TLV not
established. |
EFFECTS OF
SHORT-TERM EXPOSURE: The substance
is irritating to the gastrointestinal tract.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged
contact with skin may cause dermatitis. |
PHYSICAL PROPERTIES |
Boiling point:
313°C Melting point: -10 to -18°C Relative density (water = 1): 0.96 Solubility in water: very poor |
Flash point:
229°C c.c. Auto-ignition temperature: 448°C |
ENVIRONMENTAL DATA |
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NOTES |
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ADDITIONAL INFORMATION |
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LEGAL NOTICE
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Neither the CEC
nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this
information |
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© IPCS, CEC 1999 |
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